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Wear, as necessary, protective clothing and self-contained breathing apparatus. Any quantity of a Division 1.1, 1.2, or 1.3 material; A quantity of a Division 1.4, 1.5, or 1.6 material requiring placarding in accordance with subpart F of this part; A large bulk quantity of Division 2.1 material; A large bulk quantity of Division 2.2 material with a subsidiary hazard of 5.1; Any quantity of a material poisonous by inhalation, as defined in 171.8 of this subchapter; A large bulk quantity of a Class 3 material meeting the criteria for Packing Group I or II; A quantity of desensitized explosives meeting the definition of Division 4.1 or Class 3 material requiring placarding in accordance with subpart F of this part; A large bulk quantity of a Division 4.2 material meeting the criteria for Packing Group I or II; A quantity of a Division 4.3 material requiring placarding in accordance with subpart F of this part; A large bulk quantity of a Division 5.1 material in Packing Groups I and II; perchlorates; or ammonium nitrate, ammonium nitrate fertilizers, or ammonium nitrate emulsions, suspensions, or gels; Any quantity of organic peroxide, Type B, liquid or solid, temperature controlled; A large bulk quantity of Division 6.1 material (for a material poisonous by inhalation see paragraph (5) above); A select agent or toxin regulated by the Centers for Disease Control and Prevention under 42 CFR part 73 or the United States Department of Agriculture under 9 CFR part 121; A quantity of uranium hexafluoride requiring placarding under 172.505(b); International Atomic Energy Agency (IAEA) Code of Conduct Category 1 and 2 materials including Highway Route Controlled quantities as defined in 49 CFR 173.403 or known radionuclides in forms listed as RAM-QC by the Nuclear Regulatory Commission; A large bulk quantity of Class 8 material meeting the criteria for Packing Group I. 172.504 contains a number of notes and exceptions to these requirements. Figure 10-9 input and image HTML or a combination of the two can be used to easily add glyphicons. This requirement is particularly important for ammonium nitrate manufacturers. hoW maNy Bushels oF corN caN oNe rail taNk car oF ammoNia produce? However, untreated wooden bin construction is prohibited by this paragraph and only wood treated to prevent impregnation by ammonium nitrate prior to being placed in service is permitted. For more information you may call 202-366-6121. (3) Ammonium nitrate fertilizer, Division 5.1 (oxidizer), UN 2067. galactose (a biomass-burning sugar), or Fe(III). The purpose of ventilating an ammonium nitrate storage building during a fire event is to prevent the accumulation of highly toxic off-gas products, such as nitrogen CSHOs may cite this paragraph if the employer does not have an automatic sprinkler system for bagged ammonium nitrate storage exceeding 2500 tons. DIVISION 1.5 VERY INSENSITIVE EXPLOSIVES This section applies to: Packages that require labeling, multi-compartmented cargo tanks, and portable tanks loaded in transport vehicles or freight containers. Regardless of the hazard class, cyanide and cyanide mixtures can not be transported with acids. A package containing a cigarette lighter, or other similar device, equipped with an ignition element and containing fuel; except that a cigarette lighter or similar device subject to this paragraph may be shipped if the design of the device and its inner packaging has been examined by the Bureau of Explosives and specifically approved by the Associate Administrator for Hazardous Materials Safety. The coating or cladding must be robust enough to withstand foot and vehicular traffic such as, but not limited to, that from fork trucks, bobcats, and front-end loaders. A major provision of this legislation prohibits Federal agencies from using motor carriers rated unsatisfactory to transport hazardous materials in quantities requiring placarding. Ammonium nitrate storage facilities in high humidity and high temperature environments have a higher likelihood of clumping than those in low humidity and temperature areas. concentrated urea ammonium solution nitrate A hazmat employee (including an owner operator of a motor vehicle leased to a registered motor carrier for 30 days or more). Avoidance of cross As a hazmat employee, additional specialized training may be required based on the job function and material-specific requirements related to the handling of hazardous materials. This term includes any department, agency, or instrumentality of the United States, a State, a political subdivision of a State, or an Indian tribe described in the first sentence of this definition. Our interpretation letters explain these requirements and how they apply to particular circumstances, but they cannot create additional employer obligations. The small charges, thought at the time to be a safe practice, set off the powerful explosion. can liquid ammonium nitrate be transported by air?nh ohrv registration locations. These officials have authority for enforcing municipal building, fire, plumbing, and electrical codes as related to building occupancy permits. ammonium particles nitrate deposited silicon explosives vaporization enhanced Farm Product Warehousing and Storage - 493130 Treated wood must remain impregnable to ammonium nitrate throughout its use. Ventilation and HVAC systems designed solely for employee comfort. The hazmat employer must determine the extent to which the CDL endorsement satisfies all training requirements. The term "transports" or "transportation" means any movement of property by any mode, and any loading, unloading, or storage incident thereto. All ammonium nitrate plants produce an aqueous ammonium nitrate solution through the reaction of ammonia and nitric acid in a neutralizer as follows: NH3 HNO3 NH4NO3 Approximately 60 percent of the ammonium nitrate produced in the U. S. is sold as a The records required by this rule must be produced upon reasonable demand by an authorized employee of the Department of Transportation. Although NFPA 490-1970 addresses numerous hazards associated with the storage of ammonium nitrate, some aspects of the standard, as codified in 1910.109(i), are not enforceable by OSHA as they contain requirements specific to an authority having jurisdictiontypically a municipal or state code official. 49 CFR 172.101 Hazardous Materials Table49 CFR 173.21 Forbidden Materials and Packages, Cyclotetramethylene tetranitramine (dry or unphlegmatized) (HMX), 2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more than 42 percent with inert solid, 2,2-Di-(tert-butylperoxy) butane, with more than 55 percent in solution, Di-(tert-butylperoxy) phthalate, with more than 55 percent in solution, Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent with water, Di-n-butyl peroxydicarbonate, with more than 52 percent in solution, Diacetone alcohol peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass, Diacetyl peroxide, solid, or with more than 25 percent in solution, Dibenzyl peroxydicarbonate, with more than 87 percent with water, N,N'-Dichlorazodicarbonamidine (salts of) (dry), Diethyl peroxydicarbonate, with more than 27 percent in solution, 1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic acid), Diisopropylbenzene hydroperoxide, with more than 72 percent in solution, 2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 percent with water, 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry), 2,4-Dinitroresorcinol (heavy metal salts of) (dry), 4,6-Dinitroresorcinol (heavy metal salts of) (dry), 3,5-Dinitrosalicylic acid (lead salt) (dry), Dinitrosobenzylamidine and salts of (dry), 1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry), Dipropionyl peroxide, with more than 28 percent in solution, Guanyl nitrosaminoguanylidene hydrazine (dry), 2,2',4,4',6,6'-Hexanitro-3,3'-dihydroxyazobenzene (dry), N,N'-(hexanitrodiphenyl) ethylene dinitramine (dry), Isopropylcumyl hydroperoxide, with more than 72 percent in solution, Mercury iodide aquabasic ammonobasic (Iodide of Millon's base), Methyl ethyl ketone peroxide, in solution with more than 9 percent by mass active oxygen, Methyl isobutyl ketone peroxide, in solution with more than 9 percent by mass active oxygen, Methyl picric acid (heavy metal salts of), Methylamine dinitramine and dry salts thereof, 6-Nitro-4-diazotoluene-3-sulfonic acid (dry), 1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acid, Perchloric acid, with more than 72 percent acid by mass, Peroxyacetic acid, with more than 43 percent and with more than 6 percent hydrogen peroxide, Phosphorus (white or red) and a chlorate, mixtures of, 2,3,4,6-Tetranitrophenyl methyl nitramine, 2,4,6-Trinitro-1,3,5-triazido benzene (dry). (See 49 CFR 107.606(a)(6) for exceptions and reciprocity.). ammonium nitrate fertilizer zimbabwe fertiliser harare chiremba 50kg 25kg shumba Ventilation systems must be in place to address fire emergencies.

This term includes an owner-operator of a motor vehicle which transports a hazardous material in commerce. Fire, breakage, spillage, or suspected radioactive contamination occurs involving a radioactive material; Fire, breakage, spillage, or suspected contamination occurs involving an infectious substance other than a diagnostic specimen or regulated medical waste; A release of a marine pollutant occurs in a quantity exceeding 450L (119 gallons) for a liquid or 400 kg (882 pounds) for a solid; or. No hazard beyond that of ordinary combustible material. : N/A - mixture Synonyms: UAN (28, 30, and 32% N), Liquid nitrogen fertilizer STCC: 2871313 1.2. Comments. COMMERCIAL DRIVERS LICENSE REGULATION APPLICABILITY : THE RULES IN THIS PART APPLY TO EVERY PERSON WHO OPERATES A COMMERCIAL MOTOR VEHICLE IN INTERSTATE, FOREIGN, OR INTRASTATE COMMERCE AND TO ALL EMPLOYEES OF SUCH PERSONS. For employers that receive ammonium nitrate prills by truck or railcar, such as at fertilizer distributor and supplier facilities, this requirement is less of a factor as the ammonium nitrate is likely received at ambient temperature due to prolonged exposure to ambient temperatures while in transit. The letter "L" for packaging passing a leakproofness test.
It has a density of 1.725 g/cm3. WebNitrogen (N) accounts for more than 80% of the total mineral nutrients absorbed by plants and it is the most widely limiting element for crop production, particularly under water deficit conditions. including trade names and synonyms. Ammonium nitrate readily absorbs moisture allowing individual prills to stick together. This list above contains some of the major responsibilities of HM carriers. DIVISION 2.3 POISONOUS OR TOXIC, This class includes materials that are Compressed, Dissolved under Pressure, or Pressurized Cryogenic Liquids, and Liquefied Gases, Includes materials whose Flash Point (FP) is not more than 141F, DIVISION 4.1 FLAMMABLE SOLID Warehouses shall have adequate ventilation or be capable of adequate ventilation in case of fire. Use of these materials without protection from contact with ammonium nitrate can create conditions that could potentially lead to an explosion. General shipper responsibilities are contained in 49 CFR Part 173. If you have questions on the application of these or any requirements in 29 CFR 1910.109(i), please call Mary Lynn, Director, Office of Chemical Process Safety and Enforcement Initiatives at (202) 693-1995 or Jeffrey Wanko, Office of Chemical Process Safety and Enforcement Initiatives at (202) 693-2137. If the laboratory determines the wood is impregnated with ammonium nitrate, OSHA may cite under this paragraph. An official website of the United States government Here's how you know. It is used to make fertilizers and explosives. Modal specific requirements:Any additional training required by 49 CFR PARTS 174, 175, 176, or 177. Storage of Bags, Drums, and Containers of Ammonium Nitrate. Table of Hazardous Materials and Special Provisions. The 1,001 lbs. Incidents involving etiologic agents may be made to the CDC at (800) 232-0124.

Aggregate gross weight is the total weight of all hazardous materials and its packaging loaded on a single transport vehicle. TRANSPORTATION IN COMMERCE ON A PUBLIC HIGHWAY: Transportation on (across or along) roads outside of Government properties generally is transportation in commerce. The description of hazardous materials on a shipping paper is contained in section 172.202. Unless otherwise provided in this subchapter, the offering for transportation or transportation of the following is forbidden: Pipeline and Hazardous Materials Safety Administration, HAZMAT Registration Help Desk:202-366-4109, Hazardous Materials Information Center: 1-800-467-4922, Office of Governmental, International, and Public Affairs, U.S. Department of Transportation, Pipeline and Hazardous Materials Safety Administration, United States Department of Transportation, Hazardous Materials Safety Enhancement Program, National Preparedness for Response Exercise Program (PREP), United Nations Sub-Committee of Experts on the Transport of Dangerous Goods, International Civil Aviation Organization, Global Harmonization of Hazard Classification and Labeling Systems, International List of Competent Authorities, 49 CFR 173.21 Forbidden Materials and Packages, Acetyl acetone peroxide with more than 9 percent by mass active oxygen, Acetyl benzoyl peroxide, solid, or with more than 40 percent in solution, Acetyl cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent water, Acetyl peroxide, solid, or with more than 25 percent in solution, Antimony sulfide and a chlorate, mixtures of, Arsenic sulfide and a chlorate, mixtures of, Azido hydroxy tetrazole (mercury and silver salts), 4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C.), 1-Bromo-3-nitrobenzene (unstable at 56 degrees C), tert-Butyl hydroperoxide, with more than 90 percent with water, tert-Butyl peroxyacetate, with more than 76 percent in solution, n-Butyl peroxydicarbonate, with more than 52 percent in solution, tert-Butyl peroxyisobutyrate, with more than 77 percent in solution, 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate (dry), 2,4,6-Trinitroso-3-methyl nitraminoanisole, Tris, bis-bifluoroamino diethoxy propane (TVOPA). If small diameter water hoses are installed, water supply must be available for their operation in an emergency. Limited clumping that is easily broken up is expected and not a violation. WebPure solid ammonium nitrate (AN) is very safe when stored and transported correctly. phase pneumatic methods to off-load or otherwise transfer AMMONIUM NITRATE prills. For more information or to ask questions related to the hazardous materials regulations call 1-800-467-4922 or contact PHMSA at: Pipeline and Hazardous Materials Safety Administration Rg = ideal gas constant (0.7302 ft3 atm/lb-mol R) 49 USC 5101 et seq.

For transportation by vessel, shipments are authorized in accordance with the control-temperature requirements of Section 21 of the General Introduction of the International Maritime Dangerous Goods Code (IMDG Code). The shipper may accept the manufacturer's certification, specification, approval or exemption marking in determining the packaging compliance. For content of report and additional information, please see 171.15. When filling packages with hazardous materials the shipper must comply with these written instructions. The ammonium salt of nitric acid. OSHA, however, has no relevant permitting or approval authority unique to such municipal or state code officials. Liquid ammonium nitrate may be concentrated to form an ammonium nitrate "melt" for use in solids formation processes. For non-bulk packaging, technical names must be marked in parenthesis in association with the proper shipping name if required by 172.203(k). For status of approvals previously issued by the Bureau of Explosives, see 171.19 of this subchapter. Of all the shippers' (offerors') responsibilities, the requirement to properly classify a hazardous material is very important. A lock ( LockA locked padlock ) or https:// means youve safely connected to the .gov website. Secure .gov websites use HTTPS (This substitutes for the lack of performance tests in UN standards with regard to puncture resistance, abrasion resistance and metal fatigue). Agricultural Operations All motor carriers, including interstate, intrastate and foreign carriers must comply with this regulation. By continuing to use this website you are giving consent to cookies being used. In addition, water supplies and hydrants for structural firefighting must be available for crews to fight warehouse fires. The employer is also required to train their hazmat employees on the security plan. Containers of ammonium nitrate shall not be accepted for storage when the temperature of the ammonium nitrate exceeds 130 deg. F. To prevent hot spots and possible thermal decomposition, the average temperature within any ammonium nitrate container cannot exceed 130F. However, when 1,000 kg (2,205 lbs.) In a majority of countries, the detailed specification is regulated by law and the safe handling, transportation, and application of ammonium nitrate are ensured. Because NFPA 490 - 1970 still provides an interpretative basis for 1910.109(i), the ammonium nitrate provisions of 1910.109(i) apply to all industries under OSHA jurisdiction and are not limited to those using ammonium nitrate in the production of explosives. A shipment of compressed or refrigerated liquefied methane or liquefied natural gas, or other liquefied gas with a methane content of at least 85 percent, in a bulk packaging having a capacity equal to or greater than 13,248 L (3,500 gallons). 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Easily broken up is expected and not a violation relevant permitting or approval authority unique to such municipal state! Required by 49 CFR 107.606 ( a ) ( 6 ) for and! Shipping paper is contained in section 172.202, protective clothing and self-contained breathing apparatus for! Building occupancy permits of the hazard class, cyanide and cyanide mixtures can not exceed 130F is.

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